China Precious Metal Refining Technology And Equipment Leading Brand
Detailed News
Recovering Gold From Gold-plated Scrap

     

What are the methods for recovering gold from gold-plated scrap components?

A: Gold on gold-plated scrap can be stripped via pyrometallurgical, chemical or electrolytic processes. The specific methods are as follows:

(1) Lead Melting Stripping Method

First, melt electrolytic lead, then immerse the gold-plated scrap in the molten lead to dissolve the gold layer into the lead. Remove the scrap after gold stripping is completed. The gold-bearing molten lead is cast into lead bullion plates, which are then subjected to electrolysis to produce electrolytic lead, and gold is recovered from the anode slime generated during the lead electrolysis process.

(2) Thermal Expansion Stripping Method

Based on the difference in thermal expansion coefficients between gold and the base alloy, this method creates gaps between the gold layer and the base material through heating. The treated parts are then boiled in dilute sulfuric acid to make the gold layer peel off, followed by subsequent dissolution and purification to recover gold.

(3) Sodium Cyanide-Sodium m-Nitrobenzenesulfonate Stripping Method

Weigh sodium cyanide and sodium m-nitrobenzenesulfonate at a specified ratio, add them to a fixed volume of water, and the stripping solution is ready for use after the reagents are fully dissolved. Immerse the gold-plated scrap in the stripping solution preheated to 90°C, and gold will dissolve into the solution within 1 to 2 minutes. Rinse the stripped scrap thoroughly with distilled water, and the rinse water can be reused for subsequent rinsing. Adjust the pH of the diluted gold-bearing stripping solution to 1~2 with hydrochloric acid. Then recover gold from the stripping solution via cementation using zinc plates or zinc wires until the yellow tint of the solution fades completely.

(4) Iodine-Potassium Iodide Solution Stripping Method

Wash and dry the parts to be stripped, place them in a porous plastic basket, and immerse the entire basket in the stripping solution until stripping is fully completed. The filtrate is concentrated, and gold powder can be obtained via reduction with sodium sulfite.

(5) Reverse Aqua Regia Stripping Method

The stripping solution is prepared with nitric acid (HNO₃) and hydrochloric acid (HCl) at a volume ratio of 3:1. Stripping is carried out at room temperature and can be completed within 1 to 5 minutes. First separate the silver chloride (AgCl) precipitate from the gold-bearing stripping solution, then concentrate the solution to drive off residual nitrate. Gold powder can be prepared by reducing the treated solution with sodium sulfite or ferrous salts.

(6) Electrolytic Stripping Method

An aqueous solution containing 2.5% thiourea and 2.5% sodium sulfite is used as the electrolyte, with graphite as the cathode and the gold-plated scrap as the anode. Under a current density of 2 A/dm² and a cell voltage of 4.1 V, gold can be completely dissolved within 20 to 25 minutes. The formed complex cation Au[SC(NH₂)₂]²⁺ is immediately reduced to gold powder by the sodium sulfite in the electrolyte.

+8613303827570
Related Product
Related Video
Product Center
Related Cases
Contact Us
We'll get in touch with you right away to provide detailed product info and tech insights sincerely.