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etching solution extraction and copper electrowinning

     

etching solution  extraction and copper electrowinning:

The printed circuit board (PCB) corrosion process generates a large amount of corrosion sludge. This sludge contains copper ions ("100-170g/L" ammonia, salts, and ammonium chloride). The traditional handling method is that PCB manufacturers sell the sludge as waste液 and use it as raw material to produce sponge copper and other products via precipitation methods. However, a large amount of ammonia ions and a small amount of copper ions cannot be effectively utilized, leading to resource waste.

First process: This process uses direct electrowinning. Direct electrowinning is a method where the corrosion sludge is directly Electrolytic deposition extraction high-purity electrolytic copper, reducing the copper ion concentration in alkaline corrosion sludge and then performing component optimization before reuse in production lines. If recycling utilization is not required, copper can be removed on-site for disposal, and comprehensive utilization can reduce treatment costs. Pollutants are treated to meet required concentrations.

Second process: This process uses solvent extraction - reverse extraction - electrorefining for the regeneration of corrosion sludge. The copper ions in the corrosion sludge are concentrated via leaching using a solvent extraction method, achieving non-destructive separation. The leach liquid and remaining  are then mixed and optimized to restore the corrosion performance before being returned to the production line for use. Finally, electrorefining is performed on the reverse-extracted electrolyte to obtain copper plates with purity of 99.5% or higher.

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